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    固废基地质聚合物固化沿海软土的力学机理与劣化性能研究

    Investigation of Mechanical Mechanisms and Deterioration Properties of Geological Polymers from Solid Waste for Stabilizing Coastal Soft Soils

    • 摘要: 我国沿海地区的软土承载力低,无法直接作为地基进行工程建设.此外,矿渣和电石渣等工业废渣的利用率也较低.为满足高质量发展要求,探索了矿渣-电石渣基地质聚合物固化沿海软土的宏观力学性能与微观结构发展机理.通过响应面试验和数值分析得出,矿渣、电石渣和硅酸钠的最佳掺量分别为16.8%、6.9%和3.6%(命名KDG固化剂).通过无侧限抗压强度、水稳定性、干湿循环和冻融循环试验比较了KDG固化剂与水泥在不同环境下的固化效果.在7d和28d龄期,相较于水泥固化土,KDG固化土有着更好的抗压强度、韧性、水稳性、抗干湿循环和抗冻融循环性能.根据X射线衍射(XRD)与扫描电子显微镜(SEM)测试结果,7d时KDG固化土水化产物主要为絮状水化硅酸钙(C-S-H),28d时絮状C-S-H逐渐发育形成三维网状结构,内部孔隙得到填充,促使固化土力学性能得到提高.KDG固化剂对软土的固化效果显著,提高了废渣的利用率,实现“以废治废”,符合绿色可持续发展理念,具有良好的应用前景.以期该研究对沿海软土地基处理工程和以软土为基材的预拌固化土提供一定的技术支持.

       

      Abstract: The low bearing capacity of coastal soft soils in China prevents their direct use as foundations for engineering construction.Additionally,the utilization rates of industrial waste materials such as slag and carbide slag remain low.In response to the demand for high-quality development,this study investigates the macro-mechanical properties and micro-structural development mechanisms of geological polymers derived from slag and carbide slag for the stabilization of coastal soft soils.Through response surface methodology and numerical analysis,the optimal proportions of slag,carbide slag,and sodium silicate were determined to be 16.8%,6.9%,and 3.6%,respectively,leading to the formulation of the KDG curing agent.Unconfined compressive strength,water stability,dry-wet cycling,and freeze-thaw cycling tests were conducted to compare the curing effects of KDG with that of cement under various conditions.At both 7 and 28 days,the KDG solidified soil demonstrated superior compressive strength,toughness,water stability,resistance to dry-wet cycling,and freeze-thaw cycling compared to cement solidified soil.XRD and SEM analyses revealed that the hydration products of KDG solidified soil at 7 days primarily consisted of fibrous calcium silicate hydrate (C-S-H),which evolved into a three-dimensional network structure by 28 days,effectively filling internal voids and enhancing the mechanical properties.The KDG curing agent significantly improves the stabilization of soft soils while increasing the utilization of waste materials,aligning with sustainable development principles.This research holds significant implications for the treatment of coastal soft soil foundations and the use of premixed stabilized soils based on soft materials.

       

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