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    基于Izbash方程的非达西水分渗流作用下混凝土氯离子运移研究

    Study on Chloride Ion Migration in Concrete Under Non-Darcy Water Seepage Based on Izbash Equation

    • 摘要: 水分对流效应主导非饱和混凝土内部氯离子的运移,为了探究非饱和混凝土结构的耐久性,设计了不同水胶比的C40混凝土试件.基于Izbash方程描述了比流量与水力梯度之间的关系,建立了非达西水分渗流模型,并结合Boltzmann变换推导氯离子运移模型.通过对比室内试验数据与COMSOL数值模拟结果,验证了氯离子运移模型的可靠性.研究结果表明,混凝土的表观氯离子扩散系数与渗透系数随时间的增加而逐渐减小并趋于稳定,且二者均与水胶比呈正相关;所建立的数学模型可很好地计算氯离子在混凝土内的运移过程;非达西渗流模型模拟的氯离子运移速率及运移启动时间显著低于传统达西渗流模型.以期该研究成果为优化沿海工程防腐技术提供理论支持.

       

      Abstract: The convection effect of moisture predominantly controls the transport of chloride ions within the unsaturated concrete.To examine the durability of unsaturated concrete structures,C40 concrete specimens with varying water-binder ratios were designed.A non-Darcy moisture seepage model was developed based on the Izbash equation to describe the nonlinear relationship between specific discharge and hydraulic gradient.Via Boltzmann transformation,an analytical solution for chloride ion transport was derived.The acceptability of the proposed chloride ion transport model was validated by comparing with laboratory experimental data and COMSOL numerical simulation results.The results indicate that both the apparent chloride ion diffusion coefficient and permeability coefficient of concrete decrease gradually over time and stabilize finally.Both parameters are positively correlated with the water-binder ratio.The established mathematical model can be used to accurately simulate the transport process of chloride ions within the unsaturated concrete.The chloride ion migration rate and migration start-up time for the non-Darcy seepage model are significantly lower than those for the traditional Darcy model.The research provides theoretical support for optimizing corrosion prevention techniques in coastal engineering projects.

       

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