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    初始损伤喷射混凝土复合盐侵蚀性能及机理

    Performance and Mechanism of Shotcrete with Initial Damage Subjected to Compound Salt Attack

    • 摘要: 为了探究含初始损伤缺陷的喷射混凝土受复合盐侵蚀性能,采用半浸泡和全浸泡两种方式对初始损伤喷射混凝土进行长期自然侵蚀试验,系统研究了初始损伤、浸泡方式和侵蚀盐种类对喷射混凝土自由氯离子浓度、宏观性能和微观结构的影响,分析了影响机理,并建立了初始损伤喷射混凝土侵蚀损伤演化模型.研究结果表明:初始损伤对喷射混凝土受盐侵蚀劣化过程产生了不同程度的影响.初始损伤度越大,试件同一测试深度处的自由氯离子浓度越高,受侵蚀过程中质量和相对动弹模量变化越明显,试件腐蚀程度越严重.低于0.14的初始损伤对喷射混凝土侵蚀损伤劣化过程影响较小,超过0.21的初始损伤则使喷射混凝土侵蚀劣化速度显著加快.经历180d单一盐和复合盐半浸泡侵蚀后,初始损伤为0.30的试件质量分别降低4.55%和3.82%,相对动弹模量分别降至0.39和0.53,试件表面产生了明显损伤开裂,边角出现成块脱落.初始损伤程度相同时,半浸泡作用、单一硫酸盐侵蚀对喷射混凝土的破坏程度要高于全浸泡、复合盐侵蚀.将侵蚀损伤因子表示为侵蚀龄期的指数函数,所得到的喷射混凝土损伤模型曲线与试验值吻合度较高,拟合相关系数超过0.97.SEM-EDS和XRD分析显示,受盐侵蚀后初始损伤试件内部钙矾石晶体分布更加密集,晶体衍射峰高度明显高于基准组,初始损伤的存在增加了盐溶液的侵入通道.受复合盐侵蚀的喷射混凝土XRD图谱中出现了Friedel盐晶体衍射峰,且钙矾石晶体衍射峰明显低于单一硫酸盐侵蚀组,复合盐溶液中Cl-的存在减缓了SO42-的扩散速度.

       

      Abstract: In order to explore the composite salt erosion performance of shotcrete with initial damage defects,long-term natural erosion tests on shotcrete with initial damage were carried out by partial immersion and full immersion methods.The effects of initial damage,immersion method and erosion salt type on free chloride ion concentration,macro performance and microstructure of shotcrete were systematically studied,and the influencing mechanism was analyzed.And the erosion damage evolution model of shotcrete with initial damage was established.The results show that the initial damage has different effects on the deterioration process of shotcrete subjected to salt erosion.The greater the initial damage degree,the higher the concentration of free chloride ion at the same test depth,the more obvious the change of mass and relative dynamic modulus during the erosion process,and the more serious the corrosion degree of the specimen.The initial damage below 0.14 has little effect on the deterioration process of shotcrete damage,while the initial damage exceeding 0.21 significantly accelerates the deterioration rate of corroded shotcrete.After 180 days of single salt and compound salt partial immersion erosion,the mass of the specimens with initial damage of 0.30 decreased by 4.55% and 3.82%,respectively,and the relative dynamic modulus decreased to 0.39 and 0.53,respectively.Obvious damage cracking occurred on the surface of the specimen,and block shedding appeared at the corners.While the initial damage degree is the same,the damage degree of partial immersion and single sulfate attack on shotcrete is higher than that of full immersion and compound salt attack.Under the premise that the erosion damage factor is expressed as an exponential function of the erosion age,the obtained damage model curves of shotcrete are in good agreement with the experimental values,and the fitting correlation coefficients are all over 0.97.SEM-EDS and XRD analysis showed that the distribution of ettringite crystals in the initial damage specimens after salt erosion were densely,and the height of crystal diffraction peak was significantly higher than that of the reference group,indicating that the initial damage increased the intrusion channel of salt solution.Friedel salt crystal diffraction peak appears in XRD pattern of shotcrete under compound salt attack,and the ettringite crystal diffraction peak is significantly lower than that in single sulfate attack group,indicating that the presence of Cl- in compound salt solution slows down the diffusion rate of SO42-.

       

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